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In cases of stress/illness, the GSH/GSSG ratio shifts first

TRPV1 is expressed in about 60% of vagal neurons, and TRPA1 in about 25%.[ref] In addition to chemical stimuli, TRP receptors respond to oxidative stress and systemic inflammation.[ref] Repeated activation and hyperexcitability: TRPA1 and TRPV1 receptors are often co-localized on the same cells

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Its efficacy has been supported by several studies: Antioxidant Benefits: Polypodium reduces oxidative stress, a key factor in melasma, by neutralizing free radicals and minimizing inflammation caused by UV-induced skin damage