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Acta Physico-Chim Sin, 2026, 42: 100191 Acknowledgement This work was supported by the National Natural Science Foundation of China (U24A2079), the Natural Science Foundation of Henan Province (252300421167), and the Joint Fund of Science and Technology R&D Plan of Henan Province (242301420045)

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For instance, the activated monomer mechanism (AMM) in cationic ring-opening polymerization allows fine-tuning of network stability, hydrophilicity, and crosslink densityparameters essential for synchronizing scaffold degradation with tissue remodeling kinetics